In the present study, we aimed to investigate the catalytic role of the newly reported MCM-41 -based nanocomposite in which the low acidity of this mesoporous moiety was favourably improved via the stabilization of zirconium nanoparticles and was magnetized to make a facile work-up procedure as an applicable and efficient method. The prepared Fe 3 O 4 @MCM-41 @ZrCI 2 nanocomposite was successfully characterized using different analyses and then it was favourably exploited for the synthesis of spirooxindoles as the most prominent spiro compounds. As predicted, Fe 3 O 4 @MCM- 41 @ZrCI 2 showed considerable efficiency in the promotion of the studied reaction.